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Introduction. -- General properties of organometallic complexes. -- Metal alkyls, aryls, and hydrides and related ?bonded ligands. -- Carbonyls, phosphine complexes, and liquid substitution reactions. -- Complexes of [pi]-bound ligands. -- Oxidative addition and reductive elimination. -- Insertion and elimination. -- Nucleophilic and electrophilic addition and abstraction. -- Homogeneous catalysis. -- Physical methods in organometallic chemistry. -- Metal-ligand multiple bonds. -- Applications of organometallic chemistry. -- Clusters and the metal-metal bond. -- Applications to organic synthesis. -- Paramagnetic, high-oxidation-state, and high-coordination-number complexes. -- Bioorganometallic chemistry. -- Useful texts on allied topics. -- Major reaction types. -- Solutions to problems.
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