서지주요정보
그물구조상 수지촉매를 이용한 에틸렌 및 프로필렌의 벤젠알킬화 반응 = Benzene alkylation with ethylene and prophlene using macroreticular resin catalysts
서명 / 저자 그물구조상 수지촉매를 이용한 에틸렌 및 프로필렌의 벤젠알킬화 반응 = Benzene alkylation with ethylene and prophlene using macroreticular resin catalysts / 김명수.
저자명 김명수 ; Kim, Myung-Soo
발행사항 [서울 : 한국과학기술원, 1982].
Online Access 원문보기 원문인쇄

소장정보

등록번호

4101789

소장위치/청구기호

학술문화관(문화관) 보존서고

MCE 8201

SMS전송

도서상태

이용가능

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반납예정일

초록정보

The alkylations of benzene with ethylene and propylene were performed in a fixed bed reactor by two types of macrorecticular ion exchange resin catalyst, Amberlyst 15 and Amberlyst XN-1010. External mass transfer resistance could be neglected when the flow rate of reaction mixture was over 500 ml/min (STP), and the macropore diffusion resistance could be neglected because the reaction rate was independent of the size of resin particle. The experimental data on the reaction rates can be correlated fairly well with the Rideal Kinetics, from which the reaction rate constants and the adsorption equilibrium constants were estimated. The activation energies of ethylation and propylation were as follows. ◁수식 삽입▷(원문을 참조하세요) The resin catalyst shows a higher activity in propylation than in ethylation. This semms to be due to the higher polarity of propylene such that propylene can easily be protonated from the acid catalyst and diffuse through the resin matrix.

서지기타정보

서지기타정보
청구기호 {MCE 8201
형태사항 [iii], 73 p. : 삽도 ; 26 cm
언어 한국어
일반주기 부록 수록
저자명의 영문표기 : Myung-Soo Kim
지도교수의 한글표기 : 임선기
지도교수의 영문표기 : Son-Ki Ihm
학위논문 학위논문(석사) - 한국과학기술원 : 화학공학과,
서지주기 참고문헌 : p. 61-64
주제 Polymers.
알킬화. --과학기술용어시소러스
고분자. --과학기술용어시소러스
Alkylation.
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