서지주요정보
폴리아크리레이트형의 주쇄에 피로리돈의 그래프트 공중합 = Graft copolymerization of pyrrolidone onto polyacrylate type backbone
서명 / 저자 폴리아크리레이트형의 주쇄에 피로리돈의 그래프트 공중합 = Graft copolymerization of pyrrolidone onto polyacrylate type backbone / 임종찬.
발행사항 [서울 : 한국과학기술원, 1981].
Online Access 원문보기 원문인쇄

소장정보

등록번호

4001373

소장위치/청구기호

학술문화관(문화관) 보존서고

MAC 8125

휴대폰 전송

도서상태

이용가능

대출가능

반납예정일

리뷰정보

초록정보

The studies on the copolymerization of N-acryloyl pyrrolidone and methyl methacrylate and graft copolymerization of pyrrolidone onto polyacrylate backbone were carried out. Monomer reactivity ratio values for N-acryloyl pyrrolidone - methyl methacrylate system were calculated by Fineman - Ross equation and Kelen - Tudos equation. It was found that the copolymer of N-acryloyl pyrrolidone and methyl methacrylate has randomly distributed acyl lactam function on the acrylate polymer backbone ($r_1$, $r_2$=0.97). It was also found that poly (N-acryloyl pyrrolidone-co-methyl methacrylate) was effective as a polymeric initiator of anionic polymerization of pyrrolidone. The maximum conversion, percent graft and viscosity were 61%, 2080% and 2.28 (dl/g), respectively. In this paper, we discussed the effects of reaction time, polymeric initiator concentration, catalyst concentration and temperature on the conversion, percent graft and viscosity in graft copolymerization of pyrrolidone onto polyacrylate type backbone.

서지기타정보

서지기타정보
청구기호 {MAC 8125
형태사항 [ii], 44 p. : 삽도 ; 26 cm
언어 한국어
일반주기 저자명의 영문표기 : Jong-Chan Lim
지도교수의 한글표기 : 최삼권
지도교수의 영문표기 : Sam-Kwon Choi
학위논문 학위논문(석사) - 한국과학기술원 : 화학과,
서지주기 참고문헌 : p. 42-43
주제 Methyl methacrylate.
그라프트 공중합. --과학기술용어시소러스
피롤리돈. --과학기술용어시소러스
폴리아크릴산 에스테르. --과학기술용어시소러스
Graft copolymers.
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