The synthesis of 1,2-Dichlorodifluorocyclopropene had been carried out by the fluorination of tetrachlorocyclopropene. 1-Lithio-2-chlorodifluorocyclopropene was prepared through the lithium-chlorine exchange reaction with 1,2-Dichlorodifluorocyclopropene and n-Butyllithium.
CNDO/2 calculation was carried out on hexafluorocyclopropane, tetrafluorocyclopropene, 1,2-Dichlorodifluorocycloprepene and 1-Lithio-2-chlorodiflurocyclopropene. A partial geometry optimization was carried out on 1-Lithio-2-chlorodifluorocyclopropene. We have obtained electronic structures, total energies, and dipole moments of these compounds.
1,2-dichlorodifluorocyclopropene은 tetrachlorocyclopropene을 fluorination 하여 합성하였다.
1,2-dichlorodifluorocyclopropene 과 n-butylithium을 반응시켜 lithium-halogen exchange reaction 을 통해서 1- lithio-2-chlorodifluorocyclopropene 을 생성하였다. 위의 화합물을 CNDO/2 계산에 의해 전자구조 및 에너지와 dipole moments 을 계산하였다.
또한 1-lithio-2-chlorodifluorocyclopropene에 대한 geometry optimization 을 행하였다.
