서지주요정보
1-(2-페닐시클로프로필)-2-비닐시클로프로판의 중합 = Polymerization of 1-(2-phenylcyclopropyl)-2-vinylcyclopropyl)-2-vinylcyclopropane
서명 / 저자 1-(2-페닐시클로프로필)-2-비닐시클로프로판의 중합 = Polymerization of 1-(2-phenylcyclopropyl)-2-vinylcyclopropyl)-2-vinylcyclopropane / 이성호.
저자명 이성호 ; Lee, Soung-Ho
발행사항 [대전 : 한국과학기술원, 1992].
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소장정보

등록번호

8002662

소장위치/청구기호

학술문화관(문화관) 보존서고

MAC 92021

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도서상태

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초록정보

In the study of ring-opening polymerization of vinylcyclopropanes, 1-(2-phenylcyclopropyl)-2-vinylcyclopropane(PC-VCP) which is homotriene system of biscyclopropane was prepared and its polymerization behavior was investigated. Polymerization of PC-VCP was carried out with radical initiators and photo initiator under various condition. PC-VCP polymerized in high conversion with DTBP at 120℃, and in rather low conversion with AIBN and BPO at lower temperatures. However, it failed to polymerize by benzoin methyl ether as photo initiator in 300nm UV radiation. The characterization of the polymer structure by $^1H$-NMR, $^{13}C$-NMR and IR specta indicated that the polymerization proceeded in mixed mode of 1,2-, 1,5-and 1,8-type. The polymerization mode was very much affected by the temperature. When performed at the low temperature, the reaction proceeded in high degree of double ring-opening.

서지기타정보

서지기타정보
청구기호 {MAC 92021
형태사항 iii, 41 p. : 삽도 ; 26 cm
언어 한국어
일반주기 저자명의 영문표기 : Soung-Ho Lee
지도교수의 한글표기 : 조의환
지도교수의 영문표기 : I-Whan Cho
학위논문 학위논문(석사) - 한국과학기술원 : 화학과,
서지주기 참고문헌 : p. 38-40
주제 Ultraviolet radiation.
개환 중합. --과학기술용어시소러스
자외선 조사. --과학기술용어시소러스
비닐 화합물. --과학기술용어시소러스
Ring-opening polymerization.
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