서지주요정보
(An) investigation of intercalation-induced stresses generated during lithium transport through $Li_{1-δ}CoO_2$ film electrode by using a laser beam deflection method = 레이져 빔 반사법을 이용한 $Li_{1-δ}CoO_2$ 박막 전극내 리튬 이동시 유발되는 응력에 관한 연구
서명 / 저자 (An) investigation of intercalation-induced stresses generated during lithium transport through $Li_{1-δ}CoO_2$ film electrode by using a laser beam deflection method = 레이져 빔 반사법을 이용한 $Li_{1-δ}CoO_2$ 박막 전극내 리튬 이동시 유발되는 응력에 관한 연구 / Tae-Seok Jang.
발행사항 [대전 : 한국과학기술원, 2004].
Online Access 원문보기 원문인쇄

소장정보

등록번호

8015086

소장위치/청구기호

학술문화관(문화관) 보존서고

MAME 04026

휴대폰 전송

도서상태

이용가능(대출불가)

사유안내

반납예정일

리뷰정보

초록정보

The present work explores the intercalation-induced stresses generated during lithium transport through sputter-deposited $Li_{1-\delta}CoO_2$ film electrode by using a laser beam deflection method combined with galvanostatic intermittent titration technique, cyclic voltammetry and potentiostatic current transient technique. From the stress changes, Δσ, simultaneously recorded along with the galvanostatic intermittent titration charge/discharge curves and the cyclic voltammogram, it was noted that Δσ varied remarkably in the $single-α-phase-region$ as well as in the two-phase-region, but it remained almost constant in the single-β-phase-region during the lithium intercalation/deintercalation. From the comparison between the values of Δα measured experimentally and calculated theoretically, it was suggested that the origins of Δσ in the single-α-phase-region and two-phase-region are the molar volume contraction/expansion of the α-phase and the lattice parameter mismatch between the α-phase and β-phase, respectively. From Δσ simultaneously obtained along with the potentiostatic current transient, it was found that the value of Δσ due to the phase transformation was almost constant regardless of the applied potential step, and that it coincided well with the value of Δσ obtained from the Δσ vs. lithium stoichiometry curve in the two-phase-region. Furthermore, the value of Δσ decreased slightly with increasing number of cycle of the lithium intercalation/deintercalation. From the SEM micrograph of the surface morphology of the $Li_{1-\delta}CoO_2$ film, it was noted that this stress relaxation causes the cracking of the Li_{1-\delta}CoO_2$ film.

서지기타정보

서지기타정보
청구기호 {MAME 04026
형태사항 vii, 73 p. : 삽화 ; 26 cm
언어 영어
일반주기 저자명의 한글표기 : 장태석
지도교수의 영문표기 : Su-Il Pyun
지도교수의 한글표기 : 변수일
학과명칭변경 : 재료공학과가 신소재공학과로 변경됨
학위논문 학위논문(석사) - 한국과학기술원 : 신소재공학과,
서지주기 Reference : p. 66-73
QR CODE

책소개

전체보기

목차

전체보기

이 주제의 인기대출도서