서지주요정보
Formation of self-assembled nanostructures from polymer-grafted single-wall carbon nanotubes = 단일벽 카본나노튜브와 폴리머간의 화학적 결합에 의한 자기조립형 나노구조체 형성에 관한 연구
서명 / 저자 Formation of self-assembled nanostructures from polymer-grafted single-wall carbon nanotubes = 단일벽 카본나노튜브와 폴리머간의 화학적 결합에 의한 자기조립형 나노구조체 형성에 관한 연구 / Young-Koan Ko.
저자명 Ko, Young-Koan ; 고영관
발행사항 [대전 : 한국과학기술원, 2003].
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등록번호

8014051

소장위치/청구기호

학술문화관(문화관) 보존서고

MCBE 03002

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초록정보

Since their discovery in 1991, carbon nanotubes have intensively been investigated because of their potential applications in opto-electronics, membranes and storaging materials. Recently most of the reported functionalizations of single walled carbon nanotubes (SWNTs) have been base on the use of nanotubes having carboxylic acid groups in their side-wall and end-parts. While previous studies of chemical modifications of SWNTs emphasized the solubility and functionality of them, our research is being progressed in the direction of creating new class of self-assembling nano-structured material from SWNT-polymer building block. The Polymer-grafted SWNTs was synthesized by treating shortened SWNTs with $SOCl_2$, followed by reaction with various polymers. Transmission electron microscopy (TEM) reveals that poly(butadiene) (PB)-grafted SWNTs self-organize in a selective solvent to form a micelle-like core-shell morphology. In this self-assembled nanostructure, a PB core is surrounded by SWNT bundles. A similar core-shell morphology is observed in poly(ethylene glycol) (PEG)-grafted SWNT systems. The tendency of these systems to form micelles originates from the strong association between polymer chains covalently linked to the side-walls of SWNTs. The polymer attachment at the side-walls of the nanotubes was verified by direct visualization of Au (gold) grafting sites on functionalized SWNT in Au-grafted SWNT system. This aggregation behavior resembles the self-assembly of graft copolymers in dilute solution. Our findings open up exciting possibilities for the fabrication of novel self-assembling structures based on nanotubes, and provide a new approach for building a variety of superstructures. Unlike the previous self-assembling materials, this new materials will give high stable and ordered nanostructures, since the mechanical and electronic property of the carbon nanotubes are already well known, based on the previous theoretical and experimental results on the carbon nanotubes.

서지기타정보

서지기타정보
청구기호 {MCBE 03002
형태사항 vi, 46 p. : 삽도 ; 26 cm
언어 영어
일반주기 저자명의 한글표기 : 고영관
지도교수의 영문표기 : Hee-Tae Jung
지도교수의 한글표기 : 정희태
학위논문 학위논문(석사) - 한국과학기술원 : 생명화학공학과,
서지주기 Reference : p. 43-46
주제 single-wall carbon nanotube
building block
nanostructure
self-assembly
카본나노튜브
빌딩블럭
나노구조체
자기조합
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