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산화-환원 ALD 증착법에 의해 형성된 Nickel 박막의 특성에 관한 연구 = A study on the nickel thin films formed by oxidation-reduction ALD
서명 / 저자 산화-환원 ALD 증착법에 의해 형성된 Nickel 박막의 특성에 관한 연구 = A study on the nickel thin films formed by oxidation-reduction ALD / 채정헌.
저자명 채정헌 ; Chae, Jung-Hun
발행사항 [대전 : 한국과학기술원, 2002].
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8013666

소장위치/청구기호

학술문화관(문화관) 보존서고

DMS 02028

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Signal delays and electromigration failures at interconnects are important problems for future integrated devices. Copper, which has both a lower electroresistivity and a higher electromigration resistance than aluminum, is expected to be widely used as an alternative material for future interconnection lines. Copper can be deposited using several techniques, including physical vapor deposition (PVD), chemical vapor deposition (CVD), and electroplating (EP). PVD is an inadequate method of copper deposition due to its inherent inability to deposit conformal thin films on scaled-down holes and trench lines. As an alternative, CVD of copper has been widely investigated, but has the disadvantage of poor adhesion to diffusion barrier metals. To address this issue, we performed atomic layer deposition (ALD) of nickel thin films. Nickel was selected as a glue layer, since nickel and copper form a complete solid solution. Many researchers have examined CVD of nickel using hydrogen gas. These CVD nickel layers were unsuitable as glue layers because they had large grains, with a minimum 20 nm grain diameter, and continuous films could only be obtained for thicknesses of at least 300 nm, which was too thick for the intended use. In this thesis, atomic layer deposition (ALD) of nickel for the glue layer application is studied with overcoming some problems in CVD. In ALD, when reactants are supplied during non-overlapping pulses in order to prevent gas phase reactions, ALD can achieve near perfect step coverage and precise control of film thickness at an atomic scale. Recently, ALD of elementary metals, such as copper, titanium, and tantalum, has been reported by P. Martensson and R. Solanki using $Cu(thd)_2$ and $Cu(hfac)_2$, respectively, as copper precursors, and by S. M. Rossnagel using $TiCl_4$ for Ti and $TaCl_5$ for Ta. Most of these studies performed elementary metal ALD by directly reducing the metal precursors with hydrogen or hydrogen radicals. In this thesis, I demonstrate that nickel thin films can also be formed through the ALD method using a deposition cycle consisting of two consecutive chemical reaction steps: an oxidizing and a reducing step. ALD of nickel thin films was carried out on $TiN(15 nm)/SiO_2(100 nm)/Si$ wafers at a deposition temperature and pressure of 165℃ and 400 Pa (3 Torr), respectively, in a cold-walled reactor. Solid bis(cyclopentadienyl)-nickel (nickelocene or $Ni(cp)_2$) was used as a metal-organic (MO) nickel precursor; it was held in a stainless steel container heated to 50℃ and carried by 100 sccm of argon gas. One cycle of nickel ALD consisted of two consecutive chemical reaction steps. First, the nickel precursor adsorbed on the film surface was decomposed and oxidized by water vapor; then, the atomic layer of nickel oxide formed in the previous step was reduced to metal by hydrogen radicals. The oxidizing step consisted of exposure to $Ni(cp)_2$ vapor, an argon purge period, water vapor exposure, and another argon purge, while the reducing step consisted of exposure to the hydrogen radical followed by a final argon purge. An argon flush was inserted between each reactant gas pulse to isolate the reactants from each other. In order to ignite the reaction and keep the hydrogen radical synchronized with the deposition cycle, a rectangular-shaped electrical power wave was applied between the upper and lower electrodes. To maintain a uniform gas distribution, a showerhead was used as the upper electrode; it was capacitively coupled with an RF (13.56 MHz) radical source and operated at powers of 150 and 50 W. The lower electrode, on which the wafer resides, was grounded. Film thickness was analyzed by transmission electron microscopy (TEM), and the film morphology and step coverage were analyzed by field emission scanning electron microscopy (FESEM). The film composition was measured using auger electron spectroscopy (AES), while the chemical state was measured using x-ray photoelectron spectroscopy (XPS). Preliminary experiments attempted to reduce the nickel precursor directly with the hydrogen radical. All deposition conditions were the same as the nickel deposition conditions, except there was no water vapor exposure. After 200 deposition cycles with $Ni(cp)_2$ and hydrogen radicals only, no metallic film formed on the substrate, except for some particles that could be rubbed off. This suggests that the hydrogen radical itself cannot completely decompose the MO precursor of nickel, $Ni(cp)_2$, and is unable to easily generate volatile hydrocarbon compounds from cyclopentadienyl to leave elemental nickel on the film surface. A new approach was devised to replace the direct reduction of a nickel precursor by a hydrogen radical. In this investigation, the MO precursor was first oxidized by water vapor, one of the most chemically active oxidants, to remove cyclopentadienyl from the nickel precursor. The nickel oxides thus formed were then reduced into elementary nickel by hydrogen radicals. To generate the hydrogen radical, plasma power was set at 150 W. In order to confirm whether water vapor can remove cyclopentadienyl and make nickel oxides, ALD of nickel oxides was performed using $Ni(cp)_2$ and water and the hydrogen radical step was excluded. After 200 cycles of nickel oxide ALD, dark, deep-blue thin films were deposited. AES analysis showed that the deposited films contained 71 at% nickel, 13 at% oxygen, and 16 at% carbon, and XPS analysis showed that the films were composed of a mixture of elementary nickel and NiO. This proved that the nickel precursor reacts with water vapor at a deposition temperature of 165℃, although many carbon and oxygen impurities still remain in the grown film. As already described, each nickel ALD cycle consisted of the sequential injection of $Ni(cp)_2$ vapor -argon purge -water vapor -argon purge -hydrogen radical -argon purge. The initial experimental results showed that an elementary nickel metal thin film was deposited by the ALD method using two consecutive chemical steps. After 80 cycles of nickel ALD, a thin, continuous nickel film was deposited. The nickel was polycrystalline, and although it was only about 15 nm thick, it was continuous. This can be favorably compared to the minimum 300-nm thickness necessary to obtain a continuous nickel layer through conventional CVD, which creates a large grain size. The ALD-produced film has continuity with a far thinner film than the CVD-produced film. A cross-sectional SEM image of a nickel thin film shows excellent conformality over high aspect ratio holes. This nickel thin film was deposited on sputtered TaN, which has holes 0.3㎛ in diameter and 1㎛ deep. As expected from the inherent ability of ALD, the nickel films grown by this method showed excellent step coverage and no variation dependant on growth position, such as on the bottom or sidewall of the holes or the substrate field surface. The oxygen and carbon impurity levels in the films were measured on films thicker (40 nm) than those deposited under normal conditions in order to eliminate any effects of the underlying TiN layer. The AES spectrum of the deposited film after a slight sputtering surface of the film was deposited with an RF power of 150 W. The peak-to-peak values of carbon and oxygen were very low, indicating small impurity levels. The effect of RF power on impurity concentrations in the nickel thin film was investigated. As the RF power increased, the carbon concentration in the thin films decreased from 18 to 5 at%. $Ni(cp)_2$ gives high levels of carbon impurities in the CVD processes, with from 3~5 up to 16 at% carbon incorporated due to easy reactions between absorbed neighboring precursors. Unfortunately, a carbon concentration of 5 at% is generally too high, since so much carbon may affect the electrical properties of the nickel thin film, although these were optimum deposition conditions otherwise. The resistivity of 15-nm-thick thin films was between 25 and 30 μΩㆍcm. Since the resistivity of bulk nickel is 6.84 μΩㆍcm, the higher resistivities in the films were deemed to be due to surface scattering effects and the excessive carbon content. There was a very low oxygen concentration in the deposited thin film, regardless of the RF power used, and the peak-to-peak value for oxygen shown by the AES was negligible in both cases. These results indicate that supplying $Ni(cp)_2$, water, and hydrogen radicals sequentially can make oxygen-free metallic nickel films with small levels of carbon impurities. The hydrogen radical sharply reduced the levels of both carbon and oxygen contaminants. In order to test the glue layer ability of the nickel thin film, the adhesion of copper to it was tested using the adhesive tape peel test. After ALD of nickel thin films, 1-㎛-thick CVD copper thin films were deposited without a break in the vacuum. The copper films deposited on the nickel layer did not peel off in the test; the nickel glue layer sandwiched between the copper and TiN barrier metal greatly improved the adhesion between the layers.

서지기타정보

서지기타정보
청구기호 {DMS 02028
형태사항 xi, 95 p. : 삽도 ; 26 cm
언어 한국어
일반주기 저자명의 영문표기 : Jung-Hun Chae
지도교수의 한글표기 : 강상원
지도교수의 영문표기 : Sang-Won Kang
수록잡지명 : "Atomic layer deposition of nickel by the reduction of preformed nickel oxide". Electrochemical and solid-state letters, v.5 iss.6, pp. C64-C66 (2002)
학위논문 학위논문(박사) - 한국과학기술원 : 재료공학과,
서지주기 참고문헌 수록
주제 원자층 단위 증착법
니켈
Atomic Layer Deposition
Nickel
glue layer
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