서지주요정보
$Al_2O_3-TiC-Ti$ 복합체의 연소헙성과 치밀화 = Combustion synthesis and densification of $Al_2O_3-TiC-Ti$ composites
서명 / 저자 $Al_2O_3-TiC-Ti$ 복합체의 연소헙성과 치밀화 = Combustion synthesis and densification of $Al_2O_3-TiC-Ti$ composites / 조철희.
발행사항 [대전 : 한국과학기술원, 1996].
Online Access 원문보기 원문인쇄

소장정보

등록번호

8006537

소장위치/청구기호

학술문화관(문화관) 보존서고

MMS 96045

휴대폰 전송

도서상태

이용가능(대출불가)

사유안내

반납예정일

리뷰정보

초록정보

The combustion synthesis of $Al_2O_3-TiC-Ti$ composite by self-propagating reaction from a powder mixture of $TiO_2,$ Al, and C was investigated. The combustion wave quenching technique which can freeze the combustion wave front was used to analyze the intermediate phase formed during the combustion reaction. The reaction was composed of the aluminothermic reduction of $TiO_2$ and the reaction of $TiC$ formation which were occured in series. The aluminothermic reduction of $TiO_2$ was preferentially initiated at about 1000℃ with aid of the melting of Al and the capillary spreading of Al melt between $TiO_2$ particles. It was passed through the intermediate phases of oxygen- deficient titanium oxides and the liquid solution made of Ti, Al, and O. And $Al_2O_3$ grains were formed and grew in the liquid phase so that a composition of liquid phase was continuously altered from the Al-rich to the Ti-rich to be finally in the solubilty limit of Al in Ti melt. The aluminothermic reduction of $TiO_2$ finally produced $Al_2O_3$ and Ti-rich phase. The reaction of TiC formation was the last stage and started at about the melting point of Ti. The formation of three-dimensionally interconnected $Al_2O_3$ structure which was typical in the combustion synthesis of $TiO_2-Al-C$ system was mainly due to the high combustion temperature which was come from the reaction between Ti and C in the latest stage of the combustion reaction. The decrease of the combustion temperature by the addition of TiC diluent and the decrease of the content of C in the reactant could change the structure of $Al_2O_3$ skeleton from the interconnected one to the isolated one. This isolated structure showed the superior densification behaviour than the interconnected one when the as-synthesized product was hot-pressed at the temperature of 1460℃. Therefore, it could be concluded that the microstructural control of the combustion-synthesized product was possilble by the control of the adiabatic temperature in $Al_2O_3-TiC-Ti$ composites and was the important factor in the SHS densification.

서지기타정보

서지기타정보
청구기호 {MMS 96045
형태사항 iv, 85 p. : 삽화 ; 26 cm
언어 한국어
일반주기 저자명의 영문표기 : Churl-Hee Cho
지도교수의 한글표기 : 김도경
지도교수의 영문표기 : Do-Kyung Kim
학위논문 학위논문(석사) - 한국과학기술원 : 재료공학과,
서지주기 참고문헌 : p. 78-85
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