서지주요정보
KDP 계열 강유전-반강유전 혼합결정의 구조적 유리상에 관한 연구 = Study on the structural glass phase in KDP type ferroelectric and antiferroelectric mixed crystals
서명 / 저자 KDP 계열 강유전-반강유전 혼합결정의 구조적 유리상에 관한 연구 = Study on the structural glass phase in KDP type ferroelectric and antiferroelectric mixed crystals / 신홍기.
발행사항 [대전 : 한국과학기술원, 1993].
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8003244

소장위치/청구기호

학술문화관(문화관) 보존서고

DPH 93014

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Mixed crystals of $Rb_{1-x}(NH_4)_xH_2P_{1-y}As_yO_4$(RADPA-xy) and $Cs_{1-x}(NH_4)_xH_2AsO_4$(CADA-X) are studied for various mixing concentraions (x,y)by Raman scattering and dielectric measurements in the temperature range from temperature to T=15K. Low temperature Raman spectra of RADPA(x=0.55, y=0.65), RADA(x=0.35, y=1) and CADA(x=0.2) show a gradual change with the spectral bands maintaining one to one correspondence with the paraelectric spectra, implying the glass transition rather than the structural phase transition. Temperature dependence of the Raman spectral change seems to show that condensation of the $B_2$ symmetry soft mode band, the intensity saturation of E mode $NH_4$ librational band and frequency changes of $\nu_2$ mode $PO_4/AsO_4$ internal vibrations are all correlated to each other with each one related to a different sapect of the freezing dynamics of the proton glass. Low temperature diectric peittivities RADPA(x=0.55, y=0.65) and CADA(x=0.2)mixed crystals also show the dielectric dispersion which is a typical behaviour of the dipolar glass freezing. For RADPA(x=0.61, y=0.65) mixed crystal, besides dielectric dispersion, some thermal hysteresis reminiscent of the phase transition with structural change is observed below $T_g$ in the real part of dielectric permittivity. At present, however, it is not clear whether the thermal hysteresis is due to structural phase transition or local symmetry breaking frequently observed in mixed crystals.

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서지기타정보
청구기호 {DPH 93014
형태사항 ii, 93 p. : 삽화 ; 26 cm
언어 한국어
일반주기 저자명의 영문표기 : Hong-Kee Shin
지도교수의 한글표기 : 김종진
지도교수의 영문표기 : Jong-Jean Kim
학위논문 학위논문(박사) - 한국과학기술원 : 물리학과,
서지주기 참고문헌 : p. 89-93
주제 강유전체. --과학기술용어시소러스
Raman 산란. --과학기술용어시소러스
유리 구조. --과학기술용어시소러스
Ferroelectric crystals.
Raman effect.
Dielectric measurements.
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