5-페닐시클로옥텐의 합성과 메타테시스 개환 중합 = Synthesis and ring-opening metathesis polymerization of 5-phenylcyclooctene

• 서명 / 저자: 5-페닐시클로옥텐의 합성과 메타테시스 개환 중합 = Synthesis and ring-opening metathesis polymerization of 5-phenylcyclooctene / 정상원.
• 발행사항: [대전 : 한국과학기술원, 1990].

5-Phenylcyclooctene was synthesized and its ring-opening metathesis polymerization were investigated. The monomer was synthesized by selective epoxidation of cis-1,5-cyclocotadiene and its substitution of phenyl Grignard reagent. Polymerizations of 5-phenylcyclocotene provided high polymer in 33% yield with the use of $WCl_6/EtAlCl_2$, but gave oligomer with the use of $WCl_6/Et_2AlCl$ catalyst. The polymer was found to be produced through a ring-opening polymerization by $^1H-NMR$ and IR spectra of monomer and polymer. Glass transition temperature (Tα) of poly(5-pheylcyclocotene) was determined by measurement of the DSC.

• 형태사항: iii, 50 p. : 삽화 ; 26 cm
• 언어: 한국어
• 일반주기: 저자명의 영문표기 : Sang-Won Jeong ; 지도교수의 한글표기 : 조의환 ; 지도교수의 영문표기 : I-Whan Cho
• 학위논문: 학위논문(석사) - 한국과학기술원 : 화학과,
• 서지주기: 참고문헌 : p. 31-34
• 주제: Ring-opening polymerization. ; Transition temperature. ; 화학 합성. --과학기술용어시소러스 ; 개환 중합. --과학기술용어시소러스 ; 전이 온도. --과학기술용어시소러스 ; Organic compounds --Synthesis.