The synthesis of 3,3-Difluoro-1,2-dichlorocyclopropene ha been carried out by the fluorination of tetrachlorocyclopropene.
And 1-lithio-2-chloro-3,3-difluorocyclopropene had been prepared through the lithium-halogen exchange reaction with 3,3-difluoro-1,2-dichlorocyclopropene and n-butyllithium.
Its reactions with water, acylchlorides, organometallic chlorides were described and the chemistry of these compounds was discussed.
The structures of the products were characterized by means of spectroscopic methods.
3,3 -difluoro -1,2 - dichlorocyclopropene 은 tetrachloro-cyclopropene을 fluorination하여 합성하였다.
3,3- difluoro - 1,2 - dichlorocyclopropene 과 n - butyllithitm 을 반응시켜 lithium - halogen exchange reaction 을 통해서 1 - lithio - 2 - chloro - 3,3- difluorocyclopropene 을 생성하였다.
이것의 물, acyl chloride, organometallic chlorides와의 반응이 고찰되었고 생성물의 chemistry 가 토의되었다.
생성물의 구조는 분광학적 방법에 의해서 확인하였다.