서지주요정보
Al-Li-Cu-Mg(-Ag)합금의 석출현상과 δ'상의 강화기구에 관한 연구 = Study of the precipitation behaviors and of the strengthening mechanism of δ' phase in Al-Li-Cu-Mg(-Ag) alloys
서명 / 저자 Al-Li-Cu-Mg(-Ag)합금의 석출현상과 δ'상의 강화기구에 관한 연구 = Study of the precipitation behaviors and of the strengthening mechanism of δ' phase in Al-Li-Cu-Mg(-Ag) alloys / 김제덕.
발행사항 [대전 : 한국과학기술원, 1993].
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등록번호

8003281

소장위치/청구기호

학술문화관(문화관) 보존서고

DMS 93005

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초록정보

Precipitation behaviors and strengthening mechanism in one Al-2.0wt% Li-2.8wt%Cu-0.5wt% Mg and two Al-2.0wt%Li-2.8wt%Cu-Mg-0.5wt%Ag alloys (Mg:0.5 and Mg:1.0) have been investigated by means of Vickers hardness, tensile test and transmission electron microscopy. The microstructure of the alloys primarily consist of $\delta^\prime$, $T_1$ and $S^\prime$ Phase. The coarsening kinetics of $\delta^\prime$ particles well satisfied the time law of the LSW theory and were not greatly influnced by stretching treatment. Addition of Ag and increase of Mg content tends to decrease the size of $\delta^\prime$ particles and their coarsening kinetics. The activation energy for $\delta^\prime$ coarsening in a Al-2.0wt%Li-2.8wt%Cu-0.5wt%Mg alloy is estimated to be $\sim$100kJ/mole regardless of stretch condition. The addition of Ag tends to increase the activation energy for $\delta^\prime$ coarsening to $\sim$115kJ/mole. The activation energy is $\sim$130kJ/mole in an alloy containing Ag and high Mg (1.0wt%). The stretching treatment significantly reduces the volume fraction of $\delta^\prime$ phase. The addition of Ag appears to have no appreciable effect on the $\delta^\prime$ volume fraction. In the case of the alloy containing Ag and high Mg (1.0wt%), high $\delta^\prime$ volume fraction was observed. This is due to the significant reduction of $T_1$ precipitation in this alloy. The stretching treatment greatly accelerates the nucleation kinetics of the $T_1$ phase at the expense of $S^\prime$ phase. The volume fraction of $T_1$ phase tends to increase in the case of Ag containing alloy. These are particularly true in the no-stretch condition. This is probably because of reduction of stacking fault energy by the addition of Ag. Increase of Mg content tends to accelerate the precipitation of $S^\prime$ phase at the expense of the $T_1$ precipitation. The growth rate of the $T_1$phase (and also of the $S^\prime$ phase) is significantly reduced in the stretch condition due to the overlapping of diffusion field. A model has been presented to accomodate this problem. The result is successful to predict the stretch effect on the lengthening of $T_1$ plates. The activation energy for the lengthening of $T_1$ is estimated to be 100$\sim$150 kJ/mole regardless of stretch condition in alloys without and with Ag. A similar value of activation energy (110$\sim$125 kJ/mole) is observed of the growth of $S^\prime$ rods. It is concluded that the growth of both the $T_1$ and $S^\prime$ phases is controlled by Cu diffusion along dislocations regardless of stretch condition. The nucleation of $S^\prime$ phase is greatly influnced by misfit strain energy and it tends to occur at dislocation the Burgers vector of which is nearly parallel to the [010]s $S^\prime$ direction which exhibits the maximum misfit. The variation of yield stress of the alloy has been measured as a function of aging condition. Reverting technique has been employed to distinguish the stretching effect due to the $\delta^\prime$ particles from the overall strengthening effect. The strengthening mechanism of the $\delta^\prime$ particles has been analyzed in terms of the order strengthening mechanism, in which the trailing dislocation pulls completely off from the encountering particles. The addition of Ag and increase of Mg content tends to increase the antiphase boundary energy of $\delta^\prime$ phase.

서지기타정보

서지기타정보
청구기호 {DMS 93005
형태사항 v, 129 p. : 삽화 ; 26 cm
언어 한국어
일반주기 저자명의 영문표기 : Je-Deok Kim
지도교수의 한글표기 : 박중근
지도교수의 영문표기 : Joong-Keun Park
학위논문 학위논문(박사) - 한국과학기술원 : 재료공학과,
서지주기 참고문헌 : p. 124-129
주제 Precipitation.
Aluminium-lithium alloys.
Aluminium-silver alloys.
Strengthening mechanism in solids.
석출 경화. --과학기술용어시소러스
알루미늄 합금. --과학기술용어시소러스
부정합. --과학기술용어시소러스
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