서지주요정보
$(1-x)(PbYb_{1/2}Nb_{1/2}O_3)-x(PbTiO_3)$ 고용계에서의 완화형 상전이 거동 연구 = Diffuse phase transition behavior analysis on $(1-x)(PbYb_{1/2}Nb_{1/2}O_3)-x(PbTiO_3)$
서명 / 저자 $(1-x)(PbYb_{1/2}Nb_{1/2}O_3)-x(PbTiO_3)$ 고용계에서의 완화형 상전이 거동 연구 = Diffuse phase transition behavior analysis on $(1-x)(PbYb_{1/2}Nb_{1/2}O_3)-x(PbTiO_3)$ / 유재준.
발행사항 [대전 : 한국과학기술원, 1999].
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등록번호

8009371

소장위치/청구기호

학술문화관(문화관) 보존서고

MMS 99030

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초록정보

Antiferroelectric $PbYb_\frac{1}{2}Nb_\frac{1}{2}O_{3}$[PYN] which has the first order phase transition has a complete solid solution with ferroelectric $PbTiO_3$[PT]. It was reported that there is a diffuse phase transition [DPT] region (0.10 < x < 0.25 ) in the (1-x)PYN-xPT solid solution. Dielectric constant and P-E hysteresis loop were measured in the DPT region. Also, we can measure accurately a low frequency dielectric constant by using Lock-In Amplifier(EG&G DSP 7260) from 0.1Hz to 100kHz. It can be confirmed that orthorhombic antiferroelectric phase is changed into pseudocubic DPT at x = 0.09 by the XRD analysis and the already mentioned dielectric analysis. The increase of broadness and frequency dependency of $ε_{max}$ and also the change from double loop to slim loop give evidence for increasing relaxor behavior tendency with PT content. From the experiment by Lock-In Amplifier, we obtained that an anomaly of the dielectric loss in the logarithmic frequency domain is increasing with PT concentration. It can be inferred that there is an important relationship between relaxor and anomaly tendency which is thought to originate from the increase of polar cluster's concentration. We also try to obtain the relaxation time distribution g(τ) from the complex dielectric constant by using Tikchonov regularization method. Double loop obtained by P-E hysteresis measurement is interpreted by the viewpoint of B-site ordering and related to the relaxor behavior.

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서지기타정보
청구기호 {MMS 99030
형태사항 iii, 70 p. : 삽화 ; 26 cm
언어 한국어
일반주기 저자명의 영문표기 : Jae-Joon Yu
지도교수의 한글표기 : 주웅길
지도교수의 영문표기 : Ung-Kil Joo
학위논문 학위논문(석사) - 한국과학기술원 : 재료공학과,
서지주기 참고문헌 : p. 65-67
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